(±)-1-(1-Allyl-1H-benzimidazol-2-yl)ethanol

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(±)-1-(1-Allyl-1H-benzimidazol-2-yl)ethanol

The title compound, C12H14N2O, was obtained by reaction of (±)-1-(1H-benzimidazol-2-yl)ethanol with 3-bromo-prop-1-ene. The asymmetric unit contains four crystallographically independent mol-ecules. In the crystal, mol-ecules 1 and 2 are linked via O-H⋯N hydrogen bonds, forming chains propagating along [010]. Molecules 3 and 4 are linked to these chains via O-H⋯O hydrogen bonds.

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1-Allyl-3-benzyl-1H-benzimidazol-2(3H)-one

In the title compound, C17H16N2O, the fused benzimidazol-2(3H)-one system is essentially planar, the largest deviation from the mean plane being 0.006 (2) Å for the carbonyl C atom. Its mean plane is almost perpendicular to the benzyl plane and to the allyl group, making dihedral angles of 80.6 (1) and 77.4 (3)°, respectively. The benzyl group and the allyl subsituent lie on opposite sides of t...

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1-Allyl-1H-1,3-benzimidazol-2(3H)-one

The fused five- and six-membered rings in the title compound, C(10)H(10)N(2)O, are approximately coplanar, with an r.m.s. deviation of 0.008 Å. The mean plane of the allyl group is roughly perpendicular to the mean plane of the 1,3-benzimidazol-2(3H)-one system, making a dihedral angle of 86.1 (2)°. In the crystal, each mol-ecule is linked to its symmetry equivalent partner by a pair of N-H⋯O a...

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1-Allyl-5-nitro-1H-benzimidazol-2(3H)-one

The benzimidazolone residue in the title mol-ecule, C10H9N3O3, is almost planar, with the largest deviation from the mean plane being 0.016 (2) Å for the C atom linked to the nitro group. This plane is nearly perpendicular to the 1-allyl chain as indicated by the C-N-C-C torsion angle of 90.9 (3)°. The fused-ring system makes a dihedral angle of 5.6 (3)° with the nitro group, leading to a synpe...

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2-(1H-Benzimidazol-1-yl)-1-phenyl­ethanone

In the mol-ecule of the title compound, C(15)H(12)N(2)O, the planar benzimidazole system is oriented at a dihedral angle of 80.43 (5)° with respect to the phenyl ring. In the crystal structure, non-classical inter-molecular C-H⋯N and C-H⋯O hydrogen bonds link the mol-ecules into layers parallel to the ab plane.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2012

ISSN: 1600-5368

DOI: 10.1107/s1600536812044340